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The pair posed with Hudson's pal and Mc Conaughey's wife, model Camila Alves, who donned a sheer-paneled black dress and Schutz shoes.

ET's Cameron Mathieson caught up with the 37-year-old actress on the red carpet at the gala, where she dished about her reasons for turning out to support Baby2Baby, which provides necessities to children in low-income families."I think it's always important to be involved with something that's a part of your community -- actually inside where you live and where your kids go to school," the star said."I think that one of the things that really clicks with me is a lot of children don't even go to school because they don't even have shoes," Hudson added.

"So hopefully every community has an organization that can provide those things for kids.

And [Baby2Baby does] an amazing job."ET also asked the mom of two about the story behind that great video of her singing at a birthday party for music mogul David Foster.

My kids, Danny, myself and the entire family are crazy excited!